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Inhibition of carbon steel corrosion with synergistic inhibitor mixture 
  • Calcium and zinc ions increase the inhibition effect of HEDP synergistically. 
  • The inhibition mechanism is changing, they acts as mixed inhibitors.
  • The in situ AFM technique gave morphological evidence on the synergistic effect.
Reference
I. Felhősi, Zs. Keresztes, F.H. Kármán, M. Mohai, I. Bertóti and E. Kálmán: Effect of Bivalent Cations on Corrosion Inhibition by 1-Hydroxy-Ethane-1,1-Diphosphonic Acid, J. Electrochem. Soc.,146, 961-969 (1999).

Further reading on synergism in environmentally friendly corrosion inhibitors (PDF)